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Fluctuation Electron Microscopy (FEM) examines speckle in images and diffraction patterns that arises from constructive and destructive interferences between the waves scattered by atoms in the thin material. Strong coherence between the scattered waves is necessary if structural correlations between those atoms is to be detected [1]. High spatial coherence in the illumination is crucial.more » « less
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Zjajo, Armin; Matzkevich, Itai; Du, Hongchu; Dunin-Borkowski, Rafal; Rezikyan, Aram; Treacy, Michael (, Microscopy and Microanalysis)Fluctuation Electron Microscopy (FEM) examines the scattering statistics from small volumes of thin amorphous materials in order to learn subtle details about any medium-range order (MRO) that may be present [1–4]. Both modeling and simulations show that FEM is extraordinarily sensitive to the presence of MRO, much more so than high-resolution diffraction and high-resolution imaging. The essence of FEM is to measure the 'speckliness' of diffraction (or image) data from small regions of the sample.more » « less
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McKenzie, Matthew E.; Deng, Binghui; Van Hoesen, D. C.; Xia, Xinsheng; Baker, David E.; Rezikyan, Aram; Youngman, Randall E.; Kelton, K. F. (, Scientific Reports)null (Ed.)Abstract Nucleation is generally viewed as a structural fluctuation that passes a critical size to eventually become a stable emerging new phase. However, this concept leaves out many details, such as changes in cluster composition and competing pathways to the new phase. In this work, both experimental and computer modeling studies are used to understand the cluster composition and pathways. Monte Carlo and molecular dynamics approaches are used to analyze the thermodynamic and kinetic contributions to the nucleation landscape in barium silicate glasses. Experimental techniques examine the resulting polycrystals that form. Both the modeling and experimental data indicate that a silica rich core plays a dominant role in the nucleation process.more » « less
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